A new class of atomically dispersed nickel catalysts directly converts trapped carbon dioxide (CO)2 to methane (CH4), according to Tomaz Neves García, Ph.D., a postdoctoral researcher at The Ohio State University, and colleagues.
Direct electrochemical reduction of carbon dioxide scavenging species, namely carbamates and (bi)carbonates, may be promising for carbon dioxide capture and conversion from point sources. Image credit: Neves Garcia others., doi: 10.1021/jacs.4c09744.
Carbon dioxide is the greenhouse gas responsible for most of global warming and is produced by power plants, factories, and various forms of transportation.
Typical carbon capture systems, aimed at reducing the presence of carbon dioxide in the atmosphere, reduce carbon dioxide emissions by separating carbon dioxide from other gases and converting it into useful products. .
However, the operation of these systems requires large amounts of energy, making this process difficult to implement on an industrial scale.
“Now we have found a way to save much of this precious energy by using a special nickel-based catalyst to convert the captured carbon dioxide directly into methane,” said Dr. Neves Garcia.
By using nickel atoms placed on a charged surface, Dr. Neves-Garcia and his co-authors were able to convert carbamates, a scavenging form of carbon dioxide, directly into methane.
They discovered that nickel atoms, an inexpensive and widely available catalyst, were very good at this transformation.
“We are producing high-energy fuels from low-energy molecules,” said Dr. Neves Garcia.
“What's so interesting about this is that while other companies are capturing, capturing and converting carbon in stages, we're saving energy by doing these steps simultaneously. is.”
Most importantly, streamlining the carbon capture process will help scientists reshape what they know about the carbon cycle and inform more complex strategies for faster and more efficient climate mitigation technologies. This is an important step to establish.
“We need to focus on minimizing the energy spent on carbon capture and conversion as much as possible,” said Dr. Neves García.
“So instead of performing all the capture and conversion steps separately, we can integrate it into one step and avoid wasted energy processes.”
“Many carbon capture methods are still in their infancy, but this is a promising field as researchers from a variety of disciplines are working on improvements.”
“Using renewable electricity to convert carbon dioxide into fuel has the potential to end the carbon cycle.”
“For example, when methane is burned to produce energy, it emits carbon dioxide, which can be captured and converted back into methane to support a continuous energy production cycle without adding to the planet's global warming burden. It may be possible.”
The study also represents the first time researchers have discovered that carbamates can be converted to methane using electrochemistry.
Many attempts have been made to convert the captured carbon dioxide into useful products, but so far most researchers have only shown the ability to produce carbon monoxide.
“Methane can be a very interesting product, but most importantly it opens the way to developing further processes to convert the captured carbon dioxide into other products” Neves Garcia said the doctor.
of the team work Published in Journal of the American Chemical Society.
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tomas neves garcia others. 2024. Integrated capture and conversion of carbon dioxide to methane with amines over single-atom nickel catalysts. J.Am. Chemistry. society 146 (46): 31633-31646;doi: 10.1021/jacs.4c09744
Source: www.sci.news
